SAFETY DATA SHEET

Following Regulation 1910.1200

SDS Number: 113           Date of first issue: 13 March 2013           Date of last revision: 11 July 2018

1 - Identification of product

a - Product identifier used on the label

Tradenames: Cease-Fire 2000, Cease-Fire VT 600,

b - Other means of identification

SPECIAL DUTY CASTABLES

c - Recommended use of the chemical and restrictions on use

High Temperature Thermal Insulation

d - Name, address, and telephone number

 Morgan Advanced Materials
 P. O. Box 923; Dept. 300
 Augusta, GA 30903-0923  
 Telephone: 706-796-4200

e - Emergency Phone Number

For Product Stewardship and Emergency Information:
Hotline - 1-800-722-5681
Fax - 706-560-4054

For additional SDSs and to confirm this is the most current SDS for the product, visit our web page www.morganthermalceramics.com or send a request to MT.NorthAmerica@morganplc.com

2 - Hazard Identification

a - Classification of the chemical in accordance with paragraph (d) of §1910.1200

Under OSHA HCS 2012, crystalline silica (inhaled in the form of quartz or cristobalite from occupational sources) is classified as a GHS category 1A -  Known human carcinogen.  Cements, concretes are known to cause minor irritation to eyes and skin upon contact, as precautionary measures, we have classified these products as category 2 irritant. 

b - Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200

    

 Hazard Pictograms

Signal Words

Danger

Hazard Statements

May cause cancer by inhalation.

Harmful in contact with skin

Cause eye irritation

Precaution Statements

Do not handle until all safety instructions have been read and understood.

Use respiratory protection as required; see Section 8 of the Safety Data Sheet.

Wear protective gloves, protective clothing , eye protection and face protection.

If concerned about exposure, get medical advice.

Store in a manner to minimize airborne dust. 

Dispose of waste in accordance with local, state and federal regulations.

Minimize exposure to airborne dust.

  

Emergency Overview

Respirable dust from these products may contain crystalline silica, which is known to cause respiratory disease.
(See Section 11 for more information)

c - Describe any hazards not otherwise classified that have been identified during the classification process

d - Mixture Rule

These products are mixture of various earthy material. Dust samples from these products have not been tested for their specific toxicity, but may contain more than 0.1% crystalline silica.

 . The classification . . . The hazard classification of these products were based on GHS classification of respirable crystalline silica as category 1 carcinogen.

3 - Composition / Information On Ingredients

a - Composition table

COMPONENTS                                                         Clay, Aluminum Silicate
Silica, Amorphous
Cement Alumina Chemicals
Kaolin
Crystalline Silica

CAS NUMBER
1302-93-8
7631-86-9
65997-16-2
1332-58-7
 14808-60-7 or 14464-46-1     

% BY WEIGHT
35 - 45
10 - 55
20 - 25
3 - 5
<  6

b - Common Name

(See Section 8 "Exposure Controls / Personal Protection" for exposure guidelines)

d - Impurities and Stabilizing Additives

Not applicable.

4 - First-Aid measures

a - Description of necessary measures, subdivided according to the different routes of exposure, i.e., inhalation, skin and eye contact, and ingestion

Eyes

Flush with large amounts of water for at least 15 minutes. Do not rub eyes.

Skin

Wash affected area gently with soap and water. Skin cream or lotion after washing may be helpful.

Respiratory Tract

Remove affected person to dust free location. See Section 8 for additional measures to reduce or eliminate exposure.

Gastrointestinal

Unlikely route of exposure.

c - Indication of immediate medical attention and special treatment needed, if necessary

5 - Fire-fighting measures

a - Suitable (and unsuitable) extinguishing media and

Use extinguishing media suitable for type of surrounding fire

c - Special Protective Equipment and Precautions for Firefighters

NFPA Codes:         Flammability:  0        Health:  1        Reactivity:  0        Special:  0 

b - Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products):

None

6 - Accidental Release Measures

a - Personal precautions, protective equipment, and emergency procedures

Avoid creating airborne dust. Follow routine housekeeping procedures. Vacuum only with HEPA filtered equipment. If sweeping is necessary, use a dust suppressant and place material in closed containers. Do not use compressed air for clean-up. Personnel should wear gloves, goggles and approved respirator.

b - Methods and materials for containment and cleaning up

Pick up large pieces and use a vacuum cleaner. If brushes are used, ensure that the area is wetted down first. Do not use compressed air for clean up. Do not allow to become windblown.

7 - Handling and storage

a - Precautions for safe handling

Limit the use of power tools unless in conjunction with local exhaust. Use hand tools whenever possible. Frequently clean the work area with HEPA filtered vacuum or wet sweeping to minimize the accumulation of debris. Do not use compressed air for clean-up.

b - Conditions for safe storage, including any incompatibilities

Store in a manner to minimize airborne dust.   

c - empty containers

Product packaging may contain residue. Do not reuse.

8 - Risk Management Measures / Exposures Controls / Personal Protection

a - OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet, where available

EXPOSURE GUIDELINES

MAJOR COMPONENT

OSHA PEL

ACGIH TLV

MANUFACTURER’S REG

Crystalline Silica

0.05 mg/m3  (1)

0.025 mg/m3(respirable dust)

NONE

Kaolin

15 mg/m3 (total dust)

2 mg/m(respirable dust)

NONE

Silica, Amorphous 

(80 mg/m3  ÷ % SiO2)  or  20 mppcf

10 mg/m

NONE

 (1)  OSHA new Permissible Exposure Limit (PEL) for respirable crystalline silica is 0.05 mg/m3 (8hrs-TWA), an Action Level (AL) of 0.025 mg/m3 (8hr-TWA), together with associated ancillary requirements listed under General Industry and Maritime Standard (29 CFR 1910.1053) and Construction Standards (29 CFR 1926.1153).

OTHER OCCUPATIONAL EXPOSURE LEVELS (OEL)
Ontario Canda OEL - Silica,Crystalline: Quartz/Tripoli = 0.1 mg/m3 (R); Cristobalite = 0.05 mg/m3 (R).
 Industrial hygiene standards and occupational exposure limits vary between countries and local jurisdictions.  Check which exposure levels apply to your facility and comply with local regulations.  If no regulatory dust or other standards apply, a qualified industrial hygienist can assist with a specific workplace evaluation including recommendations for respiratory protection.    

b - Appropriate Engineering Controls

Use engineering controls, such as ventilation and dust collection devices, to reduce airborne particulate concentrations to the lowest attainable level.

c - Individual protection measures, such as personal protective equipment

PPE - Skin

Wear full body clothing, gloves, hat, and eye protection as necessary to prevent skin irritation. Washable or disposable clothing may be used. If possible, do not take unwashed work clothing home. If soiled work clothing must be taken home, employers should ensure employees are trained on the best practices to minimize or avoid non-work dust exposure (e.g., vacuum clothes before leaving the work area, wash work clothing separately, rinse washer before washing other household clothes, etc.).

PPE - Eye

As necessary, wear goggles or safety glasses with side shields. 

PPE – Respiratory

When it is not possible or feasible to reduce airborne crystalline silica or particulate levels below the appropriate PEL/OEL through engineering controls, or until they are installed, employees are encouraged to use good work practices together with respiratory protection. Before providing respirators to employees (especially negative pressure type), employers should 1) monitor for airborne crystalline silica and/or dust concentrations using appropriate NIOSH analytical methods and select respiratory protection based upon the results of that monitoring , 2) have the workers evaluated by a physician to determine the workers' ability to wear respirators, and 3) implement respiratory protection training programs. Use NIOSH-certified particulate respirators (42 CFR 84), in compliance with OSHA Respiratory Protection Standard 29 CFR 1910.134 and 29 CFR 1926.103, for the particular hazard or airborne concentrations to be encountered in the work environment. For the most current information on respirator selection, contact your supplier.

9 - Physical and chemical properties

a - Appearance
Concrete like material
b -Odor
Not applicable
c - Odor Threshold
Not applicable
e- pH
Not applicable
d - Melting Point
2750°F to 2800°F
f- Initial Boiling Point/Range
Not applicable
g- Flashpoint
Not applicable
h - Evaporation Rate
Not applicable
i - Flammability
Not applicable
j - Upper/Lower Flammability or Explosive Limits
Not applicable
k - VAPOR PRESSURE
Not applicable
l - VAPOR DENSITY
Not applicable
m - Solubility
Not soluble in water
n - Relative Density
Not applicable
o - Partition Coefficient: n-Octanol/water
Not applicable
p - Auto-ignition temperature
Not applicable
q - Decomposition Temperature
Not applicable
r - Viscosity
Not applicable

10 - Stability and Reactivity

a - Reactivity

None.

b - Chemical Stability

Stable under conditions of normal use.

c - Possibility of Hazardous Reaction

Will not occur.

d - Conditions to Avoid

None

e - Incompatible Materials

Powerful oxidizers; fluorine, manganese trioxide, oxygen disulfide

f - Hazardous decomposition products

Carbon dioxide, trace amounts of carbon monoxide, hydrogen chloride, acids, aldehyde and alcohols during initial mixing of components.

11 - Toxicological information

a - TOXICOKINETICS, METABOLISM AND DISTRIBUTION

Dust samples from these products have not been tested. They may contain respirable crystalline silica.

b - Acute Toxicity

c - Epidemiology

No studies have been undertaken on humans exposed to these products in occupational environments.

Crystalline silica
Exposure to crystalline silica can cause silicosis, and exacerbate pulmonary tuberculosis and bronchitis. IARC (Monograph vol. 68, 1997) concluded that "crystalline silica from occupational sources inhaled in the form of quartz or cristobalite is carcinogenic to humans (Group 1)", and noted that "carcinogenicity in humans was not detected in all industrial circumstances studied" and "may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity".

d - Toxicology

Dust samples from these products have not been tested. They may contain respirable crystalline silica.

Crystalline silica
Some samples of crystalline silica administered to rats by inhalation and intratracheal instillation have caused fibrosis and lung cancer. Mice and hamsters, similarly exposed, develop inflammatory disease including fibrosis but no lung cancer.

Silica, amorphous
Toxic effects described in animals from single inhalation exposures of amorphous silica include upper respiratory irritation, lung congestion, bronchitis, and emphysema. Repeated inhalation exposures at concentration of 50 or 150 mg/m3 produced increased lung weights and lung changes. No progressive pulmonary fibrosis was seen and the observed lung changes were reversible. No adverse effects were observed in this study at 10 mg/m3. No animal test reports are available to define the carcinogenic, mutagenic, or reproductive effects.

International Agency for Research on Cancer and National Toxicology Program

IARC, in 1997, Monograph v.68,  classified crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to human (group 1).

The Ninth Annual Report on Carcinogens (2000), prepared by the National Toxicology Program (NTP), classified silica, crystalline (respirable size), as a substance known to be a human carcinogen.

 

 The Ninth Annual Report on Carcinogens (2000), prepared by the National Toxicology Program (NTP), classified silica, crystalline (respirable size), as a substance known to be a human carcinogen.

 

12 - Ecological information

a - Ecotoxicity (aquatic and terrestrial, where available)

These products are not reported to have any ecotoxicity effects .

c - Bioaccumulative potential

No information for the product.

d - Mobility in soil

No information for the product.

e - Other adverse effects (such as hazardous to the ozone layer

No adverse effects of this material on the environment are anticipated. 

13 - Disposal Considerations

Waste Management and Disposal

To prevent waste materials from becoming airborne during waste storage, transportation and disposal, a covered container or plastic bagging is recommended. Comply with federal, state and local regulations.

Additional information

14 - Transport information

a - UN number.

Hazard Class: Not Regulated United Nations (UN) Number: Not Applicable
Labels: Not Applicable North America (NA) Number: Not Applicable
Placards: Not Applicable Bill of Lading: Product Name

b - UN proper shipping name

Not applicable.

c - Transport hazard class(es)

Not applicable.

d - Packing group, if applicable

Not applicable.

e - Environmental hazards (e.g., Marine pollutant (Yes/No))

No.

f - Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code)

Not regulated.

g - Special precautions which a user needs to be aware of, or needs to comply with, in connection with transport or conveyance either within or outside their premises

Not applicable.

International

INTERNATIONAL
Canadian TDG Hazard Class & PIN: Not regulated
Not classified as dangerous goods under ADR (road), RID (train), IATA (air) or IMDG (ship).

15 - Regulatory information

15.1 - United States Regulations

UNITED STATES REGULATIONS
SARA Title III: This product does not contain any substances reportable under Sections 302, 304, 313 (40 CFR 372). Sections 311 and 312 apply.
OSHA: Comply with Hazard Communication Standards 29 CFR 1910.1200 and 29 CFR 1926.59 and Respiratory Protection Standards 29 CFR 1910.134 and 29 CFR 1926.103.
TSCA:All substances contained in this product are listed, if required, in the TSCA Chemical Inventory.   
California: "Silica, crystalline (airborne particles of respirable size)" is listed in Proposition 65, The Safe Drinking Water and Toxic Enforcement Act of 1986 as a chemical known to the State of California to cause cancer.
Other States: Crystalline silica products are not known to be regulated by states other than California; however, state and local OSHA and EPA regulations may apply to these products.  Contact your local agency if in doubt.

15.2 - International Regulations

INTERNATIONAL REGULATIONS
Canadian WHMIS: Class D-2A    Materials Causing Other Toxic Effects
Canadian EPA:All substances in this product are listed, as required, on the Domestic Substance List (DSL).   

16 - Other Information

initial statement

Devitrification

Product Stewardship Program

HMIS HAZARD RATING

HMIS Health                                                       1* (* denotes potential for chronic effects) 

HMIS Flammable                                                0

HMIS Reactivity                                                  0

HMIS Personal Protective Equipment                 X (To be determined by user) 

TECHNICAL DATA SHEETS

Revision Summary

OSHA PEL for Crystalline Silica revised in section 8 (June 2018).

MSDS prepared by

SDS Prepared By: MORGAN THERMAL CERAMICS ENVIRONMENTAL, HEALTH & SAFETY DEPARTMENT

Disclaimer

The information presented herein is presented in good faith and believed to be accurate as of the effective date of this Safety Data Sheet.  Employers may use this SDS to supplement other information gathered by them in their efforts to assure the health and safety of their employees and the proper use of the product. This summary of the relevant data reflects professional judgment; employers should note that information perceived to be less relevant has not been included in this SDS.  Therefore, given the summary nature of this document, Morgan Thermal Ceramics does not extend any warranty (expressed or implied), assume any responsibility, or make any representation regarding the completeness of this information or its suitability for the purposes envisioned by the user.